萘廣泛用作制備染料、樹(shù)脂、溶劑等的原料，也用作驅(qū)蟲(chóng)劑（俗稱衛(wèi)生球或樟腦丸）。起取代反應(yīng)比起加成反應(yīng)容易。下面精萘廠家從五個(gè)方面來(lái)講講萘的生產(chǎn)吧。

Naphthalene is widely used as a raw material for preparing dyes, resins, solvents, etc., and also as a repellent (commonly known as sanitary balls or camphor balls). Substitution reaction is easier than addition reaction. Let's talk about the production of naphthalene from five aspects by refined naphthalene manufacturers.

1.由石油烴制得：催化重質(zhì)重整油，催化裂化輕循環(huán)油，裂解制乙烯的副產(chǎn)焦油等；

1. Produced from petroleum hydrocarbons: catalytic heavy reforming oil, catalytic cracking light circulating oil, by-product tar from cracking to ethylene, etc;

2.由煤焦油分離，高溫煤焦油中萘約占8%-12%，將煤焦油蒸餾，切取煤油，經(jīng)脫酚，脫喹啉，蒸餾得成品萘。每噸萘消耗10t煤焦油；

2. It is separated from coal tar. Naphthalene accounts for about 8% - 12% of high temperature coal tar. Distill coal tar, cut kerosene, remove phenol, quinoline, and distill to obtain finished naphthalene. 10t coal tar is consumed per ton of naphthalene;

3.粗萘經(jīng)白土精制而得精萘；

3. Crude naphthalene is refined with clay to obtain refined naphthalene;

4.降膜分步結(jié)晶法

4. Falling film fractional crystallization method

結(jié)晶法生產(chǎn)過(guò)程由產(chǎn)品生產(chǎn)工藝系統(tǒng)、能源系統(tǒng)、氮?dú)饷芊庀到y(tǒng)和計(jì)算機(jī)控制系統(tǒng)等組成。生產(chǎn)工藝系統(tǒng)以大循環(huán)為生產(chǎn)周期，每個(gè)大循環(huán)包含4個(gè)小循環(huán)，每個(gè)小循環(huán)又包含4～6個(gè)段，每個(gè)段由結(jié)晶、部分熔融和全部熔融3個(gè)步驟組成；

The crystallization method production process consists of a product production process system, an energy system, a nitrogen sealing system, and a computer control system. The production process system takes the systemic circulation as the production cycle. Each systemic circulation contains four small cycles, and each small cycle contains 4-6 segments. Each segment consists of three steps: crystallization, partial melting and full melting;

（降膜結(jié)晶法操作工藝實(shí)例：由工業(yè)萘裝置送來(lái)的液態(tài)工業(yè)萘送入餾分槽中，當(dāng)進(jìn)行第四段結(jié)晶操作時(shí)，用泵將槽中的原料液送入動(dòng)態(tài)結(jié)晶器收集槽中。未結(jié)晶萘油與發(fā)汗液放入純度低一級(jí)的餾分槽中，全熔液可作為第五段的原料。按預(yù)定程序進(jìn)行六段結(jié)晶精制后即可得到產(chǎn)品精萘。為提高萘的提取率，可將富含硫茚的餾分送往靜態(tài)結(jié)晶器中處理，靜態(tài)結(jié)晶器所得的產(chǎn)品返回動(dòng)態(tài)結(jié)晶系統(tǒng)的相應(yīng)餾分槽，殘液可作為減水劑出售。由于該裝置同時(shí)采用動(dòng)態(tài)和靜態(tài)結(jié)晶器，既可保證較高的萘回收率，又能降低能耗。）

(Example of falling film crystallization method operation process: Liquid industrial naphthalene sent from the industrial naphthalene device is fed into the distillation tank. When the fourth stage crystallization operation is carried out, the raw material liquid in the tank is pumped into the dynamic crystallizer collection tank. Uncrystallized naphthalene oil and sweating liquid are placed in the lower purity distillation tank, and the full melt liquid can be used as the raw material for the fifth stage. After six stages of crystallization refining according to the predetermined procedure, the product refined naphthalene can be obtained. To improve the extraction rate of naphthalene Distillates rich in thionines can be sent to a static crystallizer for processing, and the products obtained from the static crystallizer are returned to the corresponding distillate tanks of the dynamic crystallization system. The residual liquid can be sold as a water reducing agent. Due to the simultaneous use of dynamic and static crystallizers in this device, it can ensure a high naphthalene recovery rate and reduce energy consumption

5.靜態(tài)分步結(jié)晶法

5. Static fractional crystallization method

將原料工業(yè)萘裝入結(jié)晶箱后進(jìn)行快速降溫，降至82℃后轉(zhuǎn)為均勻降溫，以2℃/h的降溫速度冷卻至60℃，排放富含硫茚的第一次晶析萘油，作為中間餾分待后處理。然后結(jié)晶箱內(nèi)的物料以4℃/h的速度升溫，間隔0.5h取樣一次，測(cè)定其結(jié)晶點(diǎn)，根據(jù)結(jié)晶點(diǎn)的不同，分別排入對(duì)應(yīng)餾分槽，如此進(jìn)行3～4次分步結(jié)晶，可得到較高純度的精萘。

After loading the raw material industrial naphthalene into a crystallization tank, rapid cooling is carried out, and the temperature drops to 82 ℃ before switching to uniform cooling. The cooling rate is 2 ℃/h to 60 ℃, and the first crystallization naphthalene oil rich in thionines is discharged as an intermediate fraction for post-treatment. Then, the materials in the crystallization box are heated at the rate of 4 ℃/h, sampled once every 0.5h, and their crystallization points are measured. According to the different crystallization points, they are discharged into the corresponding distillation tanks respectively. In this way, fractional crystallization is carried out for 3 to 4 times to obtain high-purity refined naphthalene.

萘的生產(chǎn)事項(xiàng)就講解到這里了，希望能夠給您好的幫助，更多事項(xiàng)就來(lái)我們網(wǎng)站http://gaozhifeng.com咨詢！

That's all for the production of naphthalene. I hope you can be helpful. For more information, please come to our website http://gaozhifeng.com consulting service